HazMat Tool — substance information

Dimethyl disulfide

HMT 15 June 2026

UN / ID: UN 2381
Hazard class: 3
Packing group: II
ERG guide: ERG 130
Special provisions: SP IB2, SP T7, SP TP2, SP TP13
Source: 49 CFR §172 (15 June 2026)

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Dimethyl disulfide

Dimethyl disulfide (DMDS) is an organic chemical compound with the molecular formula CH3SSCH3. It is a flammable liquid with an unpleasant, garlic-like odor resembling that of "leaking gas". The compound is colorless, although impure samples often appear yellowish. Wikipedia

Substance Data

Source: PubChem (HSDB, 02.12.2019)

CAS-Number

624-92-0

Flash Point

n/a

Boiling Point

n/a

Emergency Response Guide No. 130

Hazardous Materials Table

Source: 49 CFR §172 (15 June 2026)

(3) Hazard Class

3
Flammable liquids

(4) Identification number

UN 2381

(5) Packing Group

(6) Labels

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

IB2

_{Authorized IBCs:} Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1).
_{Additional Requirement:} Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized.

Browse special provision IB2

Minimum test pressure (bar)	4
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(3)

Browse special provision T7

TP2

a. The maximum degree of filling must not exceed the degree of filling determined by the following:
TP2a

Where:
t_r is the maximum mean bulk temperature during transport,
t_f is the temperature in degrees celsius of the liquid during filling, and
α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t_f) and the maximum mean bulk temperature during transportation (t_r) both in degrees celsius.
b. For liquids transported under ambient conditions α may be calculated using the formula:
TP2b

Where:
d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

TP13

Self-contained breathing apparatus must be provided when this hazardous material is transported by sea.

Browse special provision TP13

(8) Packing Authorizations (§173.***)

(8A) Exceptions	150	see 49 CFR §173.150
(8B) Non-bulk	202	see 49 CFR §173.202
(8C) Bulk	242	see 49 CFR §173.242

(9) Quantity Limits

(9A) Passenger aircraft/rail	Forbidden
(9B) Cargo aircraft only	Forbidden

(10) Vessel stowage

(10A) Location

Stowage category “B” means

(i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and
(ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

40	see 49 CFR §176.84

Source: 49 CFR §176.84

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Hazard class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	Must not be loaded, transported, or stored together in the same vehicle or facility.
	May be loaded, transported, or stored together.
	May be loaded, transported, or stored together only with restrictions.

Similar substances

UN / ID	Proper shipping name	Hazard class
UN 1556	Arsenic compounds, liquid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s	6.1
UN 1557	Arsenic compounds, solid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s	6.1
UN 1382	Potassium sulfide, anhydrous or Potassium sulfide with less than 30 percent water of crystallization	4.2
UN 1385	Sodium sulfide, anhydrous or Sodium sulfide with less than 30 percent water of crystallization	4.2
UN 0401	Dipicryl sulfide, dry or wetted with less than 10 percent water, by mass	1.1D
UN 2852	Dipicryl sulfide, wetted with not less than 10 percent water, by mass	4.1
UN 1847	Potassium sulfide, hydrated with not less than 30 percent water of crystallization	8
UN 2949	Sodium hydrosulfide with not less than 25 percent water of crystallization	8
UN 2318	Sodium hydrosulfide, with less than 25 percent water of crystallization	4.2
UN 1849	Sodium sulfide, hydrated with not less than 30 percent water	8
UN 1339	Phosphorus heptasulfide, free from yellow or white phosphorus	4.1
UN 1340	Phosphorus pentasulfide, free from yellow or white phosphorus	4.3
UN 1341	Phosphorus sesquisulfide, free from yellow or white phosphorus	4.1
UN 1343	Phosphorus trisulfide, free from yellow or white phosphorus	4.1
	Antimony sulfide and a chlorate, mixtures of	Forbidden